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Creators/Authors contains: "Volk, Michael W. R."

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  1. Abstract

    The martian dynamo’s strength and duration are essential for understanding Mars' habitability and deep interior dynamics. Although most northern volcanic terranes were likely emplaced after the martian dynamo ceased, recent data from the InSight mission show stronger than predicted crustal fields. Studying young volcanic martian meteorites offers a precise, complementary method to characterize the strength of the martian crustal field and examine its implications for past dynamo activity. We present the first rock and paleomagnetic study of nine mutually oriented samples from the martian Nakhlite meteorite Miller Range (MIL) 03346, which is well‐suited for paleomagnetic analysis due to its well‐known age (1,368 ± 83 Ma) and lack of significant aqueous, thermal, and shock overprinting. Rock magnetic analysis, including quantum diamond microscope imaging, showed that the natural remanent magnetization (NRM) is carried by Ti‐magnetite crystals containing µm‐scale ilmenite exsolution lamellae, which can accurately record ancient magnetic fields. Demagnetization of the NRM revealed a high coercivity magnetization interpreted to date from the age of eruption based on its intensity, unidirectionality, and a passing fusion crust baked contact test. Paleointensities of four samples reveal a 5.1 ± 1.5 µT paleofield, representing the most reliable martian paleointensity estimates to‐date and stronger than the 2 µT surface fields measured by InSight. Modeling shows that the observed fields can be explained by an older subsurface magnetized layer without a late, active dynamo and support a deeply buried, highly magnetized crust in the northern hemisphere of Mars. These results provide corroborating evidence for strong, small‐scale crustal fields on Mars.

     
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  2. Abstract

    Magnetic fields in the early solar system may have driven the inward accretion of the protoplanetary disk (PPD) and generated instabilities that led to the formation of planets and ring and gap structures. The Allende carbonaceous chondrite meteorite records a strong early solar system magnetic field that has been interpreted to have a PPD, dynamo, or impact‐generated origin. Using high‐resolution magnetic field imaging to isolate the magnetization of individual grain assemblages, we find that only Fe‐sulfides carry a coherent magnetization. Combined with rock magnetic analyses, we conclude that Allende carries a magnetization acquired during parent body chemical alteration at ~3.0–4.2 My after calcium aluminum‐rich inclusions in an >40 µT magnetic field. This early age strongly favors a magnetic field of nebular origin instead of dynamo or solar wind alternatives. When compared to other paleomagnetic data from meteorites, this strong intensity supports a central role for magnetic instabilities in disk accretion and the presence of temporal variations or spatial heterogeneities in the disk, such as ring and gap structures.

     
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  3. Abstract

    Interest in magnetic fields on the ancient Earth and other planetary bodies has motivated the paleomagnetic analysis of complex rocks such as meteorites that carry heterogeneous magnetizations at <<1 mm scales. The net magnetic moment of natural remanent magnetization (NRM) in such small samples is often below the detection threshold of common cryogenic magnetometers. The quantum diamond microscope (QDM) is an emerging magnetic imaging technology with ~1 μm resolution and can, in principle, recover magnetizations as weak as 10−17 Am2. However, the typically 1–100 μm sample‐to‐sensor distance of QDM measurements can result in complex (nondipolar) magnetic field maps, from which the net magnetic moment cannot be determined using a simple algorithm. Here we generate synthetic magnetic field maps to quantify the errors introduced by sample nondipolarity and by map processing procedures such as upward continuation. We find that inversions based on least squares dipole fits of upward continued data can recover the net moment of complex samples with <5% to 10% error for maps with signal‐to‐noise ratio (SNR) in the range typical of current generation QDMs. We validate these error estimates experimentally using comparisons between QDM maps and between QDM and SQUID microscope data, concluding that, within the limitations described here, the QDM is a robust technique for recovering the net magnetic moment of weakly magnetized samples. More sophisticated net moment fitting algorithms in the future can be combined with upward continuation methods described here to improve accuracy.

     
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  4. Abstract

    We present new results on the conversion of pure, undoped synthetic ferrihydrite, wet‐annealed at pH 6.56 and 90°C without stabilizing ligands, to nanophase goethite, hematite, and an intermediate magnetic phase, nanophase maghemite. Our analyses included magnetic field and temperature‐dependent properties and characterization by powder X‐ray diffraction, Mössbauer spectra, and high‐resolution transmission electron microscopy. We sampled alteration products after 0.5 hr, and then in a geometric progression to 32 hr, yielding a detailed examination of the earliest alteration phases. There are many similarities to the latest studies of pure ferrihydrite alteration but with a significant difference: We observe early appearance of oriented nanophase goethite along with a soft magnetic contribution, while rhombohedral hematite crystals form later, as reported in previous studies. Our observations attest to the non‐uniqueness of the magnetic enhancement process and to its strong dependence on environmental conditions, with important implications for use of the hematite/goethite ratio as a paleoprecipitation proxy.

     
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  5. Abstract

    Pressure remanent magnetization (PRM) is acquired when a rock is compressed in the presence of a magnetic field. This process can take place in many different environments from impact and ejection processes in space, to burial and subsequent uplifting of terrestrial rocks. In this study, we systematically study the acquisition of PRM at different pressures and temperatures, using synthetic magnetite in four different grain sizes ranging from nearly single‐domain to purely multidomain. The magnitude of the PRM acquired in a 300 μTfield is, within error, independent of the domain state of the sample. We propose that the acquisition of a PRM is mainly driven by the magnetostriction of the magnetic material. We further show that compared to a thermal remanent magnetization, the acquisition of PRM in large multidomain grains can be quite efficient, and may represent a significant component of magnetization in low‐temperature–high‐pressure environments.

     
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